Basic organic molecules serve as seed material for clouds
FRISCO — Researchers have long suspected that chemicals emitted from trees play a fundamental role in cloud formation, and recent experiments may help explain the basic molecular process.
Measuring how forest emissions influence cloud formation could help scientists develop more accurate climate models, which up to now can’t completely account for the role of clouds, cited as the biggest source of uncertainty in current climate models, according to the IPCC.
The new research by scientists at the CLOUD (Cosmics Leaving OUtdoor Droplets) experiment at CERN, including Carnegie Mellon University’s Neil Donahue, sheds light on new-particle formation.
Cloud droplets form when water vapor in the atmosphere condenses onto tiny particles. These particles are emitted directly from natural sources or human activity, or they form from precursors emitted originally as gaseous pollutants. The transformation of gas molecules into clusters and then into particles, a process called nucleation, produces more than half of the particles that seed cloud formation around the world today.
Although scientists have observed that the nucleation process nearly always involves sulfuric acid, sulfuric acid concentrations aren’t high enough to explain the rate of new particle formation that occurs in the atmosphere. This new study uncovers an indispensable ingredient to the long sought-after cloud formation recipe — highly oxidized organic compounds.
“Our measurements connect oxidized organics directly, and in detail, with the very first steps of new particle formation and growth,” said Donahue, professor of chemistry, chemical engineering, engineering and public policy, and director of CMU’s Steinbrenner Institute for Environmental Education and Research. “We had no idea a year ago that this chemistry was happening. There’s a whole branch of oxidation chemistry that we didn’t really understand. It’s an exciting time.”
Previous research has showed that organic molecules given off by pine trees, called alpha-pinene, are chemically transformed multiple times in the highly oxidizing environment of the atmosphere. Additionally, other research, including from Donahue’s lab, has suggested that such oxidized organics might take part in nucleation — both in new particle formation and in their subsequent growth.
In their latest round of experiments, Donahue and his colleagues recreated atmospheric dynamics in lab conditions. By performing experiments in the precisely controlled environment of the CLOUD chamber, the project’s scientists can change the concentrations of chemicals involved in nucleation and then measure the rate at which new particles are created with extreme precision.
After filling their experimental chamger with sulfur dioxide and pinnanediol (an oxidation product of alpha-pinene) they generated hydroxyl radicals (the dominant oxidant in Earth’s atmosphere) and watched the oxidation chemistry unfold.Using very high-resolution mass spectrometry, the scientists were able to observe particles growing from single, gaseous molecules to clusters of up to 10 molecules stuck together, as they grew molecule by molecule.
“It turns out that sulfuric acid and these oxidized organic compounds are unusually attracted to each other. This remarkably strong association may be a big part of why organics are really drawn to sulfuric acid under modern polluted conditions,” Donahue said.
After confirming that oxidized organics are involved in the formation and growth of particles under atmospheric conditions, the scientists incorporated their findings into a global particle formation model. The fine-tuned model not only predicted nucleation rates more accurately but also predicted the increases and decreases of nucleation observed in field experiments over the course of a year, especially for measurements near forests. This latter test is a strong confirmation of the fundamental role of emissions from forests in the very first stage of cloud formation, and that the new work may have succeeded in modeling that influence.